@article {384,
	title = {Study of xenon binding in cryptophane-A using laser-induced NMR polarization enhancement},
	journal = {Journal of the American Chemical Society},
	volume = {121},
	year = {1999},
	note = {J Am Chem Soc189BTTimes Cited:73Cited References Count:64},
	month = {Apr 14},
	pages = {3502-3512},
	abstract = {<p>In solution, spin-polarization transfer between laser-polarized xenon and the hydrogen nuclei of nearby molecules leads to signal enhancements in the resolved H-1 NMR spectrum, offering new opportunities for probing the chemical environment of xenon atoms. Following binding of laser-polarized xenon to molecules of cryptophane-A, selective enhancements of the H-1 NMR signals were observed. A theoretical framework for the interpretation of such experimental results is provided, and the spin polarization-induced nuclear Overhauser effects are shown to yield information about the molecular environment of xenon. The observed selective H-1 enhancements allowed xenon-proton internuclear distances to be estimated. These distances reveal structural characteristics of the complex, including the preferred molecular conformations adopted by cryptophane-A upon binding of xenon.</p>
},
	keywords = {SPECTROSCOPY},
	isbn = {0002-7863},
	doi = {Doi 10.1021/Ja9841916},
	url = {<Go to ISI>://WOS:000079884800033},
	author = {Luhmer, M. and Goodson, B. M. and Song, Y. Q. and Laws, D. D. and Kaiser, L. and Cyrier, M. C. and Pines, A.}
}
@article {396,
	title = {NMR of supercritical laser-polarized xenon},
	journal = {Chemical Physics Letters},
	volume = {292},
	year = {1998},
	note = {Chem Phys Lett112EZTimes Cited:25Cited References Count:35},
	month = {Aug 14},
	pages = {686-690},
	abstract = {<p>The feasibility of producing supercritical laser-polarized xenon for nuclear magnetic resonance (NMR) investigations was studied. Using a high-pressure capillary tube, a supercritical xenon sample (52 degrees C, 65 atm) was produced with a Xe-129 polarization approximately 140 times the equilibrium value. The polarization was observed to last for hundreds of seconds, in agreement with previous studies. These preliminary results suggest that supercritical laser-polarized xenon may be used as a polarizing solvent for numerous NMR applications. (C) 1998 Published by Elsevier Science B.V. All rights reserved.</p>
},
	keywords = {gas},
	isbn = {0009-2614},
	doi = {Doi 10.1016/S0009-2614(98)00732-5},
	url = {<Go to ISI>://WOS:000075482300049},
	author = {Haake, M. and Goodson, B. M. and Laws, D. D. and Brunner, E. and Cyrier, M. C. and Havlin, R. H. and Pines, A.}
}
