@article {511, title = {Nmr-Study of the Distribution of Aromatic-Molecules in Nay Zeolite}, journal = {Journal of Physical Chemistry}, volume = {95}, year = {1991}, note = {J Phys Chem-UsEr473Times Cited:70Cited References Count:64}, month = {Jan 10}, pages = {303-310}, abstract = {

Local and macroscopic distributions of adsorbed benzene, 1,3,5-trimethylbenzene, and hexamethylbenzene (HMB) molecules among the intracrystalline of NaY zeolite samples have been investigated by Xe-129 and multiple-quantum NMR. Xenon-129 NMR, a sensitive probe of macroscopic distributions of molecules in zeolites at room temperature, demonstrates the importance of sample heat treatment in distributing an adsorbate homogeneously throughout a collection of zeolite particles. NaY samples containing organic guests adsorbed a temperatures near the bulk species\&$\#$39; melting point produce multiple or broad xenon lines characteristic of macroscopic (i.e., interparticle) adsorbate concentration gradients. After thorough heat treatment of the samples at elevated temperatures, the xenon spectrum collapses to a single sharp line, consistent with a macroscopically uniform distribution. For HMB adsorbed in NaY, \"counting\" hydrogen clusters by multiple-quantum NMR reveals intraparticle HMB distributions consistent with one molecular per cavity at low loadings (average bulk loading less-than-or-equal-to 1 molecule per cavity) and two molecules per cavity at higher loadings.

}, keywords = {catalysts}, isbn = {0022-3654}, doi = {Doi 10.1021/J100154a056}, url = {://WOS:A1991ER47300056}, author = {Chmelka, B. F. and Pearson, J. G. and Liu, S. B. and Ryoo, R. and Demenorval, L. C. and Pines, A.} } @article {523, title = {Investigations of Adsorbed Organic-Molecules in Na-Y Zeolite by Xe-129 Nmr}, journal = {Journal of Physical Chemistry}, volume = {94}, year = {1990}, note = {J Phys Chem-UsCh532Times Cited:61Cited References Count:26}, month = {Jan 11}, pages = {27-31}, isbn = {0022-3654}, doi = {Doi 10.1021/J100364a006}, url = {://WOS:A1990CH53200006}, author = {Demenorval, L. C. and Raftery, D. and Liu, S. B. and Takegoshi, K. and Ryoo, R. and Pines, A.} } @article {568, title = {Diffusive Motion in Alkali Silicate Melts - an Nmr-Study at High-Temperature}, journal = {Geochimica Et Cosmochimica Acta}, volume = {52}, year = {1988}, note = {Geochim Cosmochim AcM3100Times Cited:79Cited References Count:67}, month = {Feb}, pages = {527-538}, isbn = {0016-7037}, doi = {Doi 10.1016/0016-7037(88)90108-1}, url = {://WOS:A1988M310000028}, author = {Liu, S. B. and Stebbins, J. F. and Schneider, E. and Pines, A.} } @article {561, title = {Phase-Incremented Multiple-Quantum Nmr Experiments}, journal = {Journal of Magnetic Resonance}, volume = {76}, year = {1988}, note = {J Magn ResonL9552Times Cited:49Cited References Count:17}, month = {Jan}, pages = {149-154}, isbn = {0022-2364}, doi = {Doi 10.1016/0022-2364(88)90209-0}, url = {://WOS:A1988L955200015}, author = {Shykind, D. N. and Baum, J. and Liu, S. B. and Pines, A.} } @article {569, title = {Probing Metal Cluster Formation in Nay Zeolite by Xe-129 Nmr}, journal = {Journal of the American Chemical Society}, volume = {110}, year = {1988}, note = {J Am Chem SocP0739Times Cited:33Cited References Count:18}, month = {Jun 22}, pages = {4465-4467}, isbn = {0002-7863}, doi = {Doi 10.1021/Ja00221a086}, url = {://WOS:A1988P073900086}, author = {Chmelka, B. F. and Ryoo, R. and Liu, S. B. and Demenorval, L. C. and Radke, C. J. and Petersen, E. E. and Pines, A.} } @article {583, title = {Distribution of Hexamethylbenzene in a Zeolite Studied by Xe-129 and Multiple-Quantum Nmr}, journal = {Journal of Physical Chemistry}, volume = {91}, year = {1987}, note = {J Phys Chem-UsL6632Times Cited:63Cited References Count:16}, month = {Dec 31}, pages = {6575-6577}, isbn = {0022-3654}, doi = {Doi 10.1021/J100311a003}, url = {://WOS:A1987L663200003}, author = {Ryoo, R. and Liu, S. B. and Demenorval, L. C. and Takegoshi, K. and Chmelka, B. and Trecoske, M. and Pines, A.} } @article {577, title = {Multiple Quantum Nmr Excitation with a One-Quantum Hamiltonian}, journal = {Chemical Physics}, volume = {114}, year = {1987}, note = {Chem PhysH4338Times Cited:45Cited References Count:16}, month = {May 15}, pages = {103-109}, isbn = {0301-0104}, doi = {Doi 10.1016/0301-0104(87)80023-X}, url = {://WOS:A1987H433800010}, author = {Suter, D. and Liu, S. B. and Baum, J. and Pines, A.} } @article {589, title = {Relaxation Mechanisms and Effects of Motion in Albite (Naalsi3o8) Liquid and Glass - a High-Temperature Nmr-Study}, journal = {Physics and Chemistry of Minerals}, volume = {15}, year = {1987}, note = {Phys Chem MinerL0167Times Cited:40Cited References Count:57}, pages = {155-162}, isbn = {0342-1791}, doi = {Doi 10.1007/Bf00308778}, url = {://WOS:A1987L016700007}, author = {Liu, S. B. and Pines, A. and Brandriss, M. and Stebbins, J. F.} }