%0 Journal Article %J Journal of Chemical Physics %D 1996 %T Determination of quadrupolar and chemical shielding tensors using solid-state two-dimensional NMR spectroscopy %A Shore, J. S. %A Wang, S. H. %A Taylor, R. E. %A Bell, A. T. %A Pines, A. %K line-shapes %X

The quadrupolar and chemical shift tensors, as well as the relative orientation of the two principle axis systems, are accurately determined using a two-dimensional nuclear magnetic resonance technique. Good agreement between experimental and simulated two-dimensional spectra is obtained for a series of rubidium and sodium compounds at multiple magnetic field strengths. Extension of this technique to correlate the quadrupolar and dipolar interactions, as well as the incorporation of a purely isotropic dimension resulting in a three-dimensional experiment is also discussed. (C) 1996 American Institute of Physics.

%B Journal of Chemical Physics %V 105 %P 9412-9420 %8 Dec 1 %@ 0021-9606 %G English %U ://WOS:A1996VV62500003 %N 21 %M WOS:A1996VV62500003 %! Determination of quadrupolar and chemical shielding tensors using solid-state two-dimensional NMR spectroscopy %R Doi 10.1063/1.472776