Determination of quadrupolar and chemical shielding tensors using solid-state two-dimensional NMR spectroscopy

TitleDetermination of quadrupolar and chemical shielding tensors using solid-state two-dimensional NMR spectroscopy
Publication TypeJournal Article
Year of Publication1996
AuthorsShore J.S, Wang S.H, Taylor R.E, Bell A.T, Pines A
JournalJournal of Chemical Physics
Volume105
Issue21
Pagination9412-9420
Date PublishedDec 1
ISBN Number0021-9606
Accession NumberWOS:A1996VV62500003
Keywordsline-shapes
Abstract

The quadrupolar and chemical shift tensors, as well as the relative orientation of the two principle axis systems, are accurately determined using a two-dimensional nuclear magnetic resonance technique. Good agreement between experimental and simulated two-dimensional spectra is obtained for a series of rubidium and sodium compounds at multiple magnetic field strengths. Extension of this technique to correlate the quadrupolar and dipolar interactions, as well as the incorporation of a purely isotropic dimension resulting in a three-dimensional experiment is also discussed. (C) 1996 American Institute of Physics.

URL<Go to ISI>://WOS:A1996VV62500003
DOI10.1063/1.472776
Short TitleDetermination of quadrupolar and chemical shielding tensors using solid-state two-dimensional NMR spectroscopy
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