Inclusion complexes oriented in thermotropic liquid-crystalline solvents studied with carbon-13 NMR

TitleInclusion complexes oriented in thermotropic liquid-crystalline solvents studied with carbon-13 NMR
Publication TypeJournal Article
Year of Publication2003
AuthorsMarjanska M., Goodson B.M, Castiglione F., Pines A
JournalJournal of Physical Chemistry B
Volume107
Issue46
Pagination12558-12561
Date PublishedNov 20
ISBN Number1520-6106
Accession NumberWOS:000186574500003
Keywordsxe-129
Abstract

The inclusion complex of cryptophane-A and chloroform dissolved in two nonchiral liquid-crystalline environments was investigated via C-13 NMR. Stable solutions of oriented complexes were prepared using aromatic (ZLI 1132) and aliphatic (ZLI 1695) thermotropic nematic liquid crystals as solvents; ordering of the complexes was manifested by the H-1-C-13 dipolar splitting of the C-13 resonance of labeled chloroform. In both solutions, the dipolar splitting for the bound ligands was substantially larger than that obtained for the free ligands, indicating a significant increase in ligand ordering upon complexation despite the absence of direct contact with the oriented solvent molecules. A similar enhancement in ordering was observed for complexed ligands compared to that for free ligands in both liquid-crystalline solvents. Also, the application of heteronuclear decoupling to the ZLI 1695 solution resulted in a reduced line width for the bound C-13 chloroform resonance, suggesting that a significant component of the observed line broadening may originate from intermolecular couplings between host and guest molecules. These results demonstrate the potential for using restored dipolar couplings to investigate structural and dynamical aspects of inclusion complexes in solution.

URL<Go to ISI>://WOS:000186574500003
DOI10.1021/Jp030431e
Short TitleInclusion complexes oriented in thermotropic liquid-crystalline solvents studied with carbon-13 NMR
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