Pulsed Fourier-Transform Nqr of N-14 with a Dc Squid

TitlePulsed Fourier-Transform Nqr of N-14 with a Dc Squid
Publication TypeJournal Article
Year of Publication1992
AuthorsHurlimann M.D, Pennington C.H, Fan N.Q, Clarke J, Pines A, Hahn E.L
JournalPhysical Review Letters
Volume69
Issue4
Pagination684-687
Date PublishedJul 27
ISBN Number0031-9007
Accession NumberWOS:A1992JE75400034
Keywordsnh4clo4
Abstract

The zero-field free induction decay of solid ammonium perchlorate at 1.5 K has been directly detected with a dc superconducting quantum interference device. The Fourier-transform spectrum consists of three sharp lines at 17.4, 38.8, and 56.2 kHz arising from pure N-14 nucLear quadrupole resonance transitions. The absence of splittings and resonance transitions from dipolar-coupled proton spins is attributed to reorientation of the ammonium groups by quantum tunneling in combination with motional averaging in the three proton levels characterized by the irreducible representation T. The measured N-14 spin-spin relaxation time is 22+/-2 ms and the spin-lattice relaxation time is 63+/-6 ms.

URL<Go to ISI>://WOS:A1992JE75400034
DOI10.1103/Physrevlett.69.684
Short TitlePulsed Fourier-Transform Nqr of N-14 with a Dc Squid
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