Approach to high-resolution ex situ NMR spectroscopy

TitleApproach to high-resolution ex situ NMR spectroscopy
Publication TypeJournal Article
Year of Publication2001
AuthorsMeriles C.A, Sakellariou D., Heise H., Moule A.J, Pines A
Date PublishedJul 6
ISBN Number0036-8075
Accession NumberWOS:000169780300032

Nuclear magnetic resonance (NMR) experiments are typically performed with samples immersed in a magnet shimmed to high homogeneity. However, there are many circumstances in which it is impractical or undesirable to insert objects or subjects into the bore of a high-field magnet. Here we present a methodology based on an adaptation of nutation echoes that provides resolved spectra in the presence of matched inhomogeneous static and radiofrequency fields, thereby opening the way to high-resolution exsitu NMR, The observation of chemical shifts is regained through the use of multiple-pulse sequences of correlated, composite z-rotation pulses, producing resolved NMR spectra of liquid samples.

URL<Go to ISI>://WOS:000169780300032
Short TitleApproach to high-resolution ex situ NMR spectroscopy
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